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Weathering of Fabrics
This section provides examples of how selected fabrics
weather outdoors in a temperate northern climate at
Russell, Ontario, Canada (45°
15' N, 75 21' W, 74 m asl). The fabrics were suspended vertically
facing ~ west into the mid-afternoon sun. A western exposure was chosen to mimic
the way a Nzi trap is normally set in the north. Technical details on
these fabrics are in Fabrics,
Blue Fabrics and
Blue Dyes.
Samples were exposed
outdoors between early May and late October
starting in 2003 for up to 6 months each year. At present, the oldest
samples have been exposed over five seasons with nearly 30 months
of cumulative exposure.
Samples were scanned at 150 pixels per inch on an HP ScanJet 4850 and are "as is" -
not washed or cleaned. Fine details of texture are not shown due to high compression; colours are
also only approximate
due to the limitations of a computer display. |
|
Key Blue & Turquoise Fabrics |
|
Phthalogen
Blue |
Cotton twill, Mount
Kenya Textiles, Kenya - Custom dyeing with Ingrain Blue 2:1 (Phthalogen Blue IF3GM
from Gharda Chemicals, India at about 4-5%) |

New |

24 mon - season 4 |

30 mon -
season 5 |
Excellent
Minor changes only, blue gets duller with time |
Started in 2003 |

New |

17 mon - season
3 |

23 mon -
season
4 |
Excellent
Minor changes only, blue gets duller with time |
Started in 2004 |
|
Sunbrella Pacific Blue |
Acrylic
marine/awning canvas, Glen Raven Mills, USA -
undisclosed solution dyeing process,
most likely mainly copper phthalocyanine pigment |

New |

24 mon - season 4 |

30 mon - season 5 |
Excellent
Almost no change, only a slight loss of original brilliance |
Started in 2003 |
|
Top Notch
Ocean Blue |
Polyester marine canvas, Marchem Coated Fabrics, USA -
undisclosed solution dyeing process,
most likely mainly copper phthalocyanine pigment |

New |

6 mon - season 1 |
Excellent
No change |
Started in 2007 |
|
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Top Notch
Blue |
Polyester marine canvas, Marchem Coated Fabrics, USA -
undisclosed solution dyeing process,
most likely just copper phthalocyanine pigment |

New |

6 mon - season 1 |
Excellent
No change |
Started in 2007 |
|
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TC
New Blue 286 |
Polyester
tsetse trap fabric, Vestergaard Frandsen, Denmark - Fabric introduced
for tsetse control applications in October 2003, unknown dye(s) |

New |

10 mon - season 2 |

16 mon - season 3 |

24 mon - season 4 |
Good/Medium
Fades in season 3, badly bleached
by the end of season 4 |
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Santiago |
Poly
/ cotton tsetse trap fabric, Ets. Gonfreville, Ivory Coast, unknown dyes
but likely using Phthalogen Blue IF3GM for dyeing the cotton fibres,
typical West African fabric |

New |

17 mon - season 3 |

23 mon - season 4 |
Good
Minor fading in season 2, moderate fading by season 4 |
Started in 2004 |
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Azur Cotton (Phthalogen) |
Cotton twill
#CV47, TDV Industries, France -
"Azur" is produced with Ingrain Blue 2:1 (Phthalogen Blue IF3GM, Dystar, Germany) in
a pad-bake process (TDV '07) |

New |

7 mon - 1.5 seasons |

13 mon - 2.5 seasons |
Good
Gradual fading and duller colour after first season |
Started in 2005
This light shade is not as sun-resistant as the darker shade from Kenya |
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Azur P/C |
Poly/cotton twill #S250,
TDV Industries, France
-
Phthalogen Blue IF3GM is part of the dyeing procedure used to produce the
"Azur" colour on P/C (TDV -
Nov 07) |

New |

7 mon - 1.5 seasons |

13 mon - 2.5 seasons |
Good/Medium
Some fading and duller colour after one season,
minor fading continues |
Started in 2005 |
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Royal Box |
Poly/cotton retail fabric,
Trigger
Poplin, USA, unknown dyes, used in recent
research on efficacy of insecticide-impregnated targets for stable flies
(Foil & Younger, 2006) |

New |

5 mon - season 1 |

11 mon - season 2 |
Fair
Fades rapidly in season 2, good for one season
only |
Started in 2006 |
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SolarMax
Royal Blue |
Nylon
Flag and Banner Cloth (Dupont, USA) - 200 Denier, unknown dye(s) |

New |

6 mon - season 1 |
Good/Medium
Minor fading
in first season |
Started in 2007 |
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SolarMax
Peacock Blue |
Nylon
Flag and Banner Cloth (Dupont, USA) - 200 Denier, unknown dye(s) |

New |

6 mon - season 1 |
Good/Medium
Minor fading
in first season |
Started in 2007 |
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SolarMax
Turquoise |
Nylon
Flag and Banner Cloth (Dupont, USA) - 200 Denier, unknown dye(s) |

New |

6 mon - season 1 |
Good/Medium
Minor fading
in first season |
Started in 2007 |
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Ethiopian
Vat Blue ? |
Ethiopian cotton from Awassa textiles (February 2006) - dark, dull blue with red tint approaching
purple, indanthrone derivative?, in current use for tsetse traps |

New |

6mon - season 1 |
Good
Depth of shade retained but brilliance of blue lost in
first season |
Started in 2007 |
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Vat Blue 6 |
Cotton bull denim - Common vat dye based on indanthrone (20 minutes in vat) |

New |

12 mon - season 2 |

17 mon - season 3 |

23 mon - season 4 |
Good
Minor fading in season 2, very gradual fading
afterwards |
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Reactive Blue 140 |
Natural bull denim cotton - Procion
Turquoise M-G (Prochem), sulphonated copper phthalocyanine,
dichlorotriazine reactive group (5% owg) |

New |

1 month |

3 mon - season 1 |

9 mon - season 2 |
Fair
Fades after several months, Good for one season only |
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RB21 + RB181 |
Reactive Blue 21 + Reactive Blue 181
Plain bleached cotton - 7% Remazol Turquoise Blue G (sulphonated
copper phthalocyanine) plus 8% Levafix Brilliant Blue E-FFN (anthraquinone) |

New |

5 months |
Poor
Fades badly after several months
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Direct Blue 86 |
Plain bleached cotton - 7% owg, sulphonated copper
phthalocyanine |

New |

1 month |

2 months |
Terrible
Fades rapidly
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Nylon
Pack Cloth |
Royal Blue - 420 Denier (Canada retail), unknown
manufacturer and dye(s). This sample illustrates the need for selecting
appropriate outdoor fabrics. Results with generic retail fabrics can be
highly unpredictable. |

New |

6 mon - season 1 |
Terrible
Fades rapidly |
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Blacks |
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Sunbrella |
Acrylic
awning fabric, Glen Raven Mills, USA -
undisclosed solution dyeing process |

New |

24 mon - season 4 |

30 mon - season 5 |
Excellent
Almost no change after five
seasons of exposure |
Started in 2003 |
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Top Notch |
Polyester
marine canvas, Marchem Coated Fabrics, USA -
undisclosed solution dyeing process |

New |

6 mon - season 1 |
Excellent
No change |
Started in 2007 |
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TC
New
Black 289 |
Polyester
tsetse trap fabric, Vestergaard Frandsen, Denmark - New fabric introduced
for tsetse control applications in October
2003, unknown dye(s) |

New |

10 mon - season 2 |

16 mon - season 3 |

24 mon - season 4 |
Good
Gradual fading, moderate loss of shade in season 4
|
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SolarMax |
Nylon
Flag and Banner Cloth (Dupont, USA) - 200 Denier, unknown dye(s) |

New |

6 mon - season 1 |
Good
Only very slight change in first season |
Started in 2007 |
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Sulphur Black |
Cotton drill, Mount
Kenya Textiles, Kenya, custom dyeing with Sulphur Black |

New |

4 mon - season 1 |

10 mon - season 2 |

16 mon - season 3 |
Fair
Fades rapidly in second season, bleached in third |
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Galaxy Twill |
Poly
/ cotton retail fabric, Fabricland, Canada - unknown dye [this is typical,
but a recent purchase faded VERY BADLY after just a few months] |

New |

4 mon |

10 mon |

16 mon |
Fair
Fades rapidly in second season, bleached in third |
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"SAFE"
FABRICS
Sunbrella
acrylic marine / awning canvas is the "gold standard" for colour
fastness in a convenient retail fabric in the correct colour of blue for
biting fly traps; both the Pacific Blue and
the Black still appear nearly-new after five seasons outdoors.
Unfortunately, excellent light-fastness is obtained at significant cost.
Top Notch
marine polyester canvas may prove to be a more
economical alternative to Sunbrella, once it is more thoroughly tested for
efficacy in traps.
Genuine Phthalogen Blue IF3GM cotton (there
are many imitations) approaches the
superb colour fastness of Sunbrella. Polyester/cottons such as "Santiago"
or "Azur" that use this specific dye for the cotton fibres also have
superior colour fastness. |
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Light Fastness of Blue Dyes
Light fastness is
only one aspect of colour fading, but is probably the most important one. It is typically measured under defined conditions
with a xenon arc lamp and expressed on a scale of 1 to 8; eight is the
highest rating (excellent). An example of a basic standard is the ISO scale for
eight blue dyeings on wool. Each level requires twice
the exposure time of the one below to cause the same degree
of fading. Technical details are explained in the following publication:
Pugh, S.L. & Guthrie, J.T. (2001) The development of light fastness
testing and light fastness standards. Review of Progress in Coloration
31, 42-56.
Deep shades normally fade at a slower rate than light shades. Light
fastness ratings are therefore expressed relative to the closest match to
six standard depths. In the ISO standard, these are defined for 20
reference colours at depths of 2/1, 1/1, 1/3, 1/6, 1/12 and 1/25 (Ingamells,
1993).
Light fastness ratings can be found in the Colour Index, or in
manufacturer's literature. The
information below is for a deep shade, e.g. as listed under ISO for depths of
1/1 or 2/1. Ratings are reproduced below for the highest rating on
cotton for depth 2/1 (or 2x normal, as listed in older publications). |
| 8 |
Phthalogen Blue - Ingrain Blue 2:1 or Bayer IF3GM (CuPc
formed in situ) |
| 7-8 |
Vat Blue 6 - Indanthrone derivative |
| 7 |
Phthalogen Blue -
Ingrain Blue 13 or Bayer IF3GK (CuPc formed in situ)
Direct Blue 86 - sulphonated CuPc derivative
Reactive Blue 19 - Remazol Brilliant Blue R (anthraquinone)
Reactive Blue 182 - Cibacron Blue F-R (copper formazan) |
| 6-7 |
Reactive Blue 4 -
Procion Brilliant Blue M-R (anthraquinone) |
| 6 |
Reactive Blue 140 - Procion
Turquoise M-G (CuPc)
Reactive Blue 15? - Cibacron Turquoise F-G
(CuPc)
Reactive Blue 71 - Procion Turquoise H-A
(CuPc)
Reactive Blue 21 - Remazol Turquoise G
(CuPc)
Reactive Blue 163 -
Procion Blue M-G (triphenodioxazine) |
| 5-6 |
Reactive Blue 204 - Cibacron Blue F-GF (triphenodioxazine) |
| 5 |
Reactive Blue 184 -
Cibacron Navy F-G (disazo) |
| 4-5 |
Reactive Blue 198 -
Procion Blue H-EGN (triphenodioxazine) |
| I
have tested most of the above for light-fastness over about six months
@5% owg on cotton twill /bull denim. I have also tested
attractiveness for biting flies relative to Phthalogen Blue in several
trapping experiments (Mihok
et al., 2006). A light fastness rating of 7-8 is
recommended for "permanent"
traps. Performance should also be tested
under real-world conditions of heat, moisture, wind, etc. Direct Blue 86,
and Remazol Brilliant Blue R faded considerably outdoors, despite a rating of 7.
I have only been able to scratch
the surface of what is possible in researching dyes as I have only been
able to test dyes in the public domain, well after patents have expired. An
example of recent developments in dye research is:
Batchelor, S.N.,
Carr, D., Coleman, C.E., Fairclough, L. & Jarvis, A. (2003)
The photofading mechanism of commercial reactive
dyes on cotton. Dyes and Pigments 59, 269-273.
This recent paper discusses two useful phthalocyanine
reactive dyes I have not
tested. These are available to the consumer from Pro
Chemical & Dye in the USA.
Procion Turquoise H-A (RB 71)
- Pro Chemical H-A Turquoise
Remazol Turquoise G (RB 21)
- Pro Chemical LR410 Turquoise
50%
Post-treatment of CuPc-based reactive
dyes with an ultraviolet blocking agent may improve light fastness, given
the excellent results achieved with application of 1% Tinuvin™
571 (Batchelor et al., 2003). For the consumer, there is a credible
home product that may be useful in this context (RIT®
Sun-Guard™). In 2006, I tested fading of fabric treated with
this product for two CuPc-based reactive dyes.
Unfortunately, there was no difference in the rate of fading with
treatment.
 | The "right blue" has turned out to be a critical
consideration in the performance of traps for biting flies. Only
brilliant blue or
greenish-blue dyes based on the copper phthalocyanine chromophore are sufficiently attractive to biting flies to warrant their use in
traps. |
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