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Weathering of Fabrics

This section provides examples of how selected fabrics weather outdoors in a temperate northern climate at Russell, Ontario, Canada (45° 15' N, 75 21' W, 74 m asl). The fabrics were suspended vertically facing ~ west into the mid-afternoon sun. A western exposure was chosen to mimic the way a Nzi trap is normally set in the north. Technical details on these fabrics are in Fabrics, Blue Fabrics and Blue Dyes.

Samples were exposed outdoors between early May and late October starting in 2003 for up to 6 months each year. At present, the oldest samples have been exposed over five seasons with nearly 30 months of cumulative exposure. Samples were scanned at 150 pixels per inch on an HP ScanJet 4850 and are "as is" - not washed or cleaned. Fine details of texture are not shown due to high compression; colours are also only approximate due to the limitations of a computer display.

 

Key Blue & Turquoise Fabrics

Phthalogen
Blue

Cotton twill,  Mount Kenya Textiles, Kenya - Custom dyeing with Ingrain Blue 2:1 (Phthalogen Blue IF3GM from Gharda Chemicals, India at about 4-5%)

New

24 mon - season 4

30 mon - season 5
Excellent
Minor changes only, blue gets duller with time
Started in 2003

New

17 mon - season 3

23 mon - season 4
Excellent
Minor changes only, blue gets duller with time
Started in 2004

Sunbrella Pacific Blue

Acrylic marine/awning canvas, Glen Raven Mills, USA - undisclosed solution dyeing process, most likely mainly copper phthalocyanine pigment

New

24 mon - season 4

30 mon - season 5
Excellent
Almost no change, only a slight loss of original brilliance
Started in 2003

Top Notch
Ocean Blue

Polyester marine canvas, Marchem Coated Fabrics, USA  - undisclosed solution dyeing process, most likely mainly copper phthalocyanine pigment

New

6 mon - season 1
Excellent
No change
Started in 2007  

Top Notch
Blue

Polyester marine canvas, Marchem Coated Fabrics, USA  - undisclosed solution dyeing process, most likely just copper phthalocyanine pigment

New

6 mon - season 1
Excellent
No change
Started in 2007  

TC New Blue 286

Polyester tsetse trap fabric, Vestergaard Frandsen, Denmark - Fabric introduced for tsetse control applications in October 2003, unknown dye(s)

New

10 mon - season 2

16 mon - season 3

24 mon - season 4
Good/Medium
Fades in season 3, badly bleached by the end of season 4

Santiago

Poly / cotton tsetse trap fabric, Ets. Gonfreville, Ivory Coast,  unknown dyes but likely using Phthalogen Blue IF3GM for dyeing the cotton fibres, typical West African fabric

New

17 mon - season 3

23 mon - season 4
Good
Minor fading in season 2, moderate fading by season 4
Started in 2004

Azur Cotton (Phthalogen)

Cotton twill #CV47,  TDV Industries, France - "Azur"  is produced with Ingrain Blue 2:1 (Phthalogen Blue IF3GM, Dystar, Germany) in a pad-bake process (TDV '07)

New

7 mon - 1.5 seasons

13 mon - 2.5 seasons
Good
Gradual fading and duller colour after first season
Started in 2005
This light shade is not as sun-resistant as the darker shade from Kenya

Azur P/C

Poly/cotton twill #S250,  TDV Industries, France - Phthalogen Blue IF3GM is part of the dyeing procedure used to produce the "Azur" colour on P/C (TDV - Nov 07)

New

7 mon - 1.5 seasons

13 mon - 2.5 seasons
Good/Medium
Some fading and duller colour after one season, minor fading continues
Started in 2005

Royal Box

Poly/cotton retail fabricTrigger Poplin, USA, unknown dyes, used in recent research on efficacy of insecticide-impregnated targets for stable flies (Foil & Younger, 2006)

New

5 mon - season 1

11 mon - season 2
Fair
Fades rapidly in  season 2, good for one season only
Started in 2006

SolarMax
Royal Blue

Nylon Flag and Banner Cloth (Dupont, USA)  - 200 Denier, unknown dye(s)

New

6 mon - season 1
Good/Medium
Minor fading
in first season
Started in 2007  

SolarMax
Peacock Blue

Nylon Flag and Banner Cloth (Dupont, USA)  - 200 Denier, unknown dye(s)

New

6 mon - season 1
Good/Medium
Minor fading
in first season
Started in 2007  

SolarMax
Turquoise

Nylon Flag and Banner Cloth (Dupont, USA)  - 200 Denier, unknown dye(s)

New

6 mon - season 1
Good/Medium
Minor fading
in first season
Started in 2007  

Ethiopian
Vat Blue ?

Ethiopian cotton from Awassa textiles (February 2006) - dark, dull blue with red tint approaching purple,  indanthrone derivative?, in current use for tsetse traps

New

6mon - season 1
Good
Depth of shade retained but brilliance of blue lost in first season
Started in 2007  

Vat Blue 6

Cotton bull denim - Common vat dye based on indanthrone (20 minutes in vat)

New

12 mon - season 2

17 mon - season 3

23 mon - season 4
Good
Minor fading in season 2, very gradual fading afterwards

Reactive Blue 140

Natural bull denim  cotton - Procion Turquoise M-G (Prochem), sulphonated copper phthalocyanine, dichlorotriazine reactive group (5% owg)

New

1 month

3 mon - season 1

9 mon - season 2
Fair
Fades after several months, Good for one season only
RB21 + RB181 Reactive Blue 21 + Reactive Blue 181
Plain bleached cotton - 7% Remazol Turquoise Blue G (sulphonated copper phthalocyanine) plus 8% Levafix Brilliant Blue E-FFN (anthraquinone)

New

5 months
Poor
Fades badly after several months
 
   
Direct Blue 86 Plain bleached cotton - 7% owg, sulphonated copper phthalocyanine

New

1 month

2 months
Terrible
Fades rapidly
 
 

Nylon
Pack Cloth

Royal Blue - 420 Denier (Canada retail),  unknown manufacturer and dye(s). This sample illustrates the need for selecting appropriate outdoor fabrics. Results with generic retail fabrics can be highly unpredictable.

New

6 mon - season 1
Terrible
Fades rapidly
   

 

Blacks

Sunbrella

Acrylic awning fabric, Glen Raven Mills, USA - undisclosed solution dyeing process

New

24 mon - season 4

30 mon - season 5
Excellent
Almost no change after five seasons of exposure
Started in 2003

Top Notch

Polyester marine canvas, Marchem Coated Fabrics, USA  - undisclosed solution dyeing process

New

6 mon - season 1
Excellent
No change
Started in 2007  

TC New
Black 289

Polyester tsetse trap fabric, Vestergaard Frandsen, Denmark - New fabric introduced for tsetse control applications in October 2003, unknown dye(s)

New

10 mon - season 2

16 mon - season 3

24 mon - season 4
Good
Gradual fading, moderate loss of shade in season 4

SolarMax

Nylon Flag and Banner Cloth (Dupont, USA)  - 200 Denier, unknown dye(s)

New

6 mon - season 1
Good
Only very slight change in first season
Started in 2007  

Sulphur Black

Cotton drill,  Mount Kenya Textiles, Kenya, custom dyeing with Sulphur Black

New

4 mon - season 1

10 mon - season 2

16 mon - season 3
Fair
Fades rapidly in second season, bleached in third

Galaxy Twill

Poly / cotton retail fabric, Fabricland, Canada - unknown dye [this is typical, but a recent purchase faded VERY BADLY after just a few months]

New

4 mon

10 mon

16 mon
Fair
Fades rapidly in second season, bleached in third

 

"SAFE" FABRICS

Sunbrella acrylic marine / awning canvas is the "gold standard" for colour fastness in a convenient retail fabric in the correct colour of blue for biting fly traps;  both the Pacific Blue and the Black still appear nearly-new after five seasons outdoors. Unfortunately, excellent light-fastness is obtained at significant cost.

Top Notch marine polyester canvas may prove to be a more economical alternative to Sunbrella, once it is more thoroughly tested for efficacy in traps.

Genuine Phthalogen Blue IF3GM cotton (there are many imitations) approaches the superb colour fastness of Sunbrella. Polyester/cottons such as "Santiago" or "Azur" that use this specific dye for the cotton fibres also have superior colour fastness.

 

Light Fastness of Blue Dyes

Light fastness is only one aspect of colour fading, but is probably the most important one. It is typically measured under defined conditions with a xenon arc lamp and expressed on a scale of 1 to 8; eight is the highest rating (excellent). An example of a basic standard is the ISO scale for eight blue dyeings on wool.  Each level requires twice the exposure time of the one below to cause the same degree of fading. Technical details are explained in the following publication:

Pugh, S.L. & Guthrie, J.T. (2001) The development of light fastness testing and light fastness standards. Review of Progress in Coloration 31, 42-56.

Deep shades normally fade at a slower rate than light shades. Light fastness ratings are therefore expressed relative to the closest match to six standard depths. In the ISO standard, these are defined for 20 reference colours  at depths of 2/1, 1/1, 1/3, 1/6, 1/12 and 1/25 (Ingamells, 1993).

Light fastness ratings can be found in the Colour Index, or in manufacturer's literature. The information below is for a deep shade, e.g. as listed under ISO for depths of 1/1 or 2/1. Ratings are reproduced below for the highest rating on cotton for depth 2/1 (or 2x normal, as listed in older publications).

8 Phthalogen Blue  - Ingrain Blue 2:1 or Bayer IF3GM (CuPc formed in situ)
7-8 Vat Blue 6 - Indanthrone derivative
7 Phthalogen Blue - Ingrain Blue 13 or Bayer IF3GK (CuPc formed in situ)
Direct Blue 86 - sulphonated CuPc derivative
Reactive Blue 19 - Remazol Brilliant Blue R (anthraquinone)
Reactive Blue 182 - Cibacron Blue F-R (copper formazan)
6-7 Reactive Blue 4 - Procion Brilliant Blue M-R (anthraquinone)
6 Reactive Blue 140 - Procion Turquoise M-G (CuPc)
Reactive Blue 15? - Cibacron Turquoise F-G (CuPc)
Reactive Blue 71 - Procion Turquoise H-A (CuPc)
Reactive Blue 21 - Remazol Turquoise G (CuPc)
Reactive Blue 163 - Procion Blue M-G (triphenodioxazine)
5-6 Reactive Blue 204 - Cibacron Blue F-GF (triphenodioxazine)
5 Reactive Blue 184 - Cibacron Navy F-G (disazo)
4-5 Reactive Blue 198 - Procion Blue H-EGN (triphenodioxazine)
I have tested most of the above for light-fastness over about six months @5% owg on cotton twill /bull denim.  I have also tested attractiveness for biting flies relative to Phthalogen Blue in several trapping experiments (Mihok et al., 2006).

A light fastness rating of 7-8 is recommended for  "permanent" traps. Performance should also be tested under real-world conditions of heat, moisture, wind, etc. Direct Blue 86, and Remazol Brilliant Blue R faded considerably outdoors, despite a rating of 7.

I have only been able to scratch the surface of what is possible in researching dyes as I have only been able to test dyes in the public domain, well after patents have expired.  An example of recent developments in dye research is:

Batchelor, S.N., Carr, D., Coleman, C.E., Fairclough, L. & Jarvis, A. (2003) The photofading mechanism of commercial reactive dyes on cotton. Dyes and Pigments 59, 269-273.

This recent paper discusses two useful phthalocyanine reactive dyes I have not tested. These are available to the consumer from Pro Chemical & Dye in the USA.


Procion Turquoise H-A (RB 71) - Pro Chemical H-A Turquoise
Remazol Turquoise G (RB 21) - Pro Chemical LR410 Turquoise 50%

Post-treatment of CuPc-based reactive dyes with an ultraviolet blocking agent may improve light fastness, given the excellent results achieved with application of 1% Tinuvin 571 (Batchelor et al., 2003). For the consumer, there is a credible home product that may be useful in this context (RIT® Sun-Guard). In 2006, I  tested fading of fabric treated with this product for  two CuPc-based reactive dyes. Unfortunately, there was no difference in the rate of fading with treatment.

bulletThe "right blue" has turned out to be a critical consideration in the performance of traps for biting flies. Only brilliant blue or greenish-blue dyes based on the copper phthalocyanine chromophore are sufficiently attractive to biting flies to warrant their use in traps.

Updated
21-Nov-2007